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Electronic Structures and Bonding Interaction of Structurally Defined Gold/Silver Superatoms

Probed by Anion Photoelectron Spectroscopy

Éditeur :

Springer

Paru le : 2025-03-13

This book focuses on ligand-protected gold clusters featuring their atomically precise compositions and unambiguous structures. They mimic electronic shell structures of atoms and are called structurally defined superatoms. The book describes the design principle of superatomic electronic structures...
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Description du livre


This book focuses on ligand-protected gold clusters featuring their atomically precise compositions and unambiguous structures. They mimic electronic shell structures of atoms and are called structurally defined superatoms. The book describes the design principle of superatomic electronic structures and the bonding theory of superatoms as revealed by gas-phase anion photoelectron spectroscopy, which is conducted by using a state-of-the-art home-built apparatus and sheds light on fundamental electronic structures such as density of states and electron affinities otherwise elusive. This study revealed that the energy level of superatomic orbitals can be tuned coarsely by the heterometal doping and finely by the stepwise ligand exchange, respectively. The bonding theory of superatoms was also developed by anion photoelectron spectroscopy of homonuclear and heteronuclear superatoms. The comprehensive review of superatoms and detailed explanation of the apparatus were described in addition to individual studies. This book provides design principles of structurally defined superatoms and stimulates future research on the chemical and physical properties of superatoms.

À propos

Auteur
Shun Ito
Éditeur
Springer
Collection
n.c
Parution
2025-03-13
Pages
112 pages
EAN papier
9789819628919

Auteur(s) du livre


Defaut-Illustration Shun Ito
Shun Ito received a PhD degree in 2024 from the University of Tokyo under the supervision of Prof. Tatsuya Tsukuda. He was appointed as a research assistant in 2019 from the forefront physics and mathematics program to drive transformation (FoPM) in the University of Tokyo, and awarded for a research fellowship for young scientists (DC1) in 2021 from Japan Society for the Promotion of Science (JSPS). He is currently a project researcher at The University of Tokyo. His research interests are physical properties of atomically precise metal clusters.

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EAN PDF
9789819628926
Prix
210,99 €
Nombre pages copiables
1
Nombre pages imprimables
11
Taille du fichier
14264 Ko
Ce livre est accessible aux handicaps informations d'accessibilité
EAN EPUB
9789819628926
Prix
210,99 €
Nombre pages copiables
1
Nombre pages imprimables
11
Taille du fichier
24965 Ko
Ce livre est accessible aux handicaps informations d'accessibilité

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